! SAPRC-07A mechanism as documented in the Condensed SAPRC07 mechansim
! report as of 4-Jan-2010
! Version "A": Uses SAPRC-99 peroxy radical operators
!
! Base Mechanism
! Atmospheric Lumped VOC Mechanism
! Base Chlorine Mechanism
! Chlorine + Atmospheric Lumped VOC Mechanism
!
REACTIONS(CM) =
! Base Mechanism
! Created from MECH09A.XLS 25-Jan-2010 14:17
!
<1> NO2 = NO + O3P # 1.0/<NO2-06>;
<2> O3P + O2 + M = O3 # 5.68e-34^-2.60;
<3> O3P + O3 =  # 8.00e-12@2060;
<4> O3P + NO = NO2 # 9.00e-32^-1.50&3.00e-11&0.60&1.00;
<5> O3P + NO2 = NO # 5.50e-12@-188;
<6> O3P + NO2 = NO3 # 2.50e-31^-1.80&2.20e-11^-0.70&0.60&1.00;
<7> O3 + NO = NO2 # 3.00e-12@1500;
<8> O3 + NO2 = NO3 # 1.40e-13@2470;
<9> NO + NO3 = 2*NO2 # 1.80e-11@-110;
<10> NO + NO + O2 = 2*NO2 # 3.30e-39@-530;
<11> NO2 + NO3 = N2O5 # 3.60e-30^-4.10&1.90e-12^0.20&0.35&1.33;
<12> N2O5 = NO2 + NO3 # 1.30e-03^-3.50@11000&9.70e+14^0.10@11080&0.35&1.33;
<13> N2O5 + H2O = 2*HNO3 # 2.50e-22;
<14> N2O5 + H2O + H2O = 2*HNO3 # 1.80e-39;
<15> NO2 + NO3 = NO + NO2 # 4.50e-14@1260;
<16> NO3 = NO # 1.0/<NO3NO-06>;
<17> NO3 = NO2 + O3P # 1.0/<NO3NO2-6>;
<18> O3 = O1D # 1.0/<O3O1D-06>;
<19> O3 = O3P # 1.0/<O3O3P-06>;
<20> O1D + H2O = 2*OH # 1.63e-10@-60;
<21> O1D + M = O3P # 2.38e-11@-96;
<22> OH + NO = HONO # 7.00e-31^-2.60&3.60e-11^-0.10&0.60&1.00;
<23> HONO = OH + NO # 1.0/<HONO-06>;
<24> OH + HONO = NO2 # 2.50e-12@-260;
<25> OH + NO2 = HNO3 # 1.80e-30^-3.00&2.80e-11&0.60&1.00;
<26> OH + NO3 = HO2 + NO2 # 2.00e-11;
<27> OH + HNO3 = NO3 %2 # 2.40e-14@-460&2.70e-17@-2199&6.50e-34@-1335;
<28> HNO3 = OH + NO2 # 1.0/<HNO3>;
<29> OH + CO = HO2 + CO2 %3 # 1.44e-13@0&3.43e-33@0;
<30> OH + O3 = HO2 # 1.70e-12@940;
<31> HO2 + NO = OH + NO2 # 3.60e-12@-270;
<32> HO2 + NO2 = HNO4 # 2.00e-31^-3.40&2.90e-12^-1.10&0.60&1.00;
<33> HNO4 = HO2 + NO2 # 3.72e-05^-2.40@10650&5.42e+15^-2.30@11170&0.60&1.00;
<34> HNO4 = 0.61*HO2 + 0.61*NO2 + 0.39*OH + 0.39*NO3 # 1.0/<HNO4-06>;
<35> HNO4 + OH = NO2 # 1.30e-12@-380;
<36> HO2 + O3 = OH # 2.03e-16^4.57@-693;
<37> HO2 + HO2 = HO2H %3 # 2.20e-13@-600&1.90e-33@-980;
<38> HO2 + HO2 + H2O = HO2H %3 # 3.08e-34@-2800&2.66e-54@-3180;
<39> NO3 + HO2 = 0.8*OH + 0.8*NO2 + 0.2*HNO3 # 4.00e-12;
<40> NO3 + NO3 = 2*NO2 # 8.50e-13@2450;
<41> HO2H = 2*OH # 1.0/<H2O2>;
<42> HO2H + OH = HO2 # 1.80e-12;
<43> OH + HO2 =  # 4.80e-11@-250;
<44> OH + SO2 = HO2 + SULF # 3.30e-31^-4.30&1.60e-12&0.60&1.00;
<45> OH + H2 = HO2 # 7.70e-12@2100;
<BR01> MEO2 + NO = NO2 + HCHO + HO2 # 2.30e-12@-360;
<BR02> MEO2 + HO2 = COOH # 3.46e-13^0.36@-780;
<BR03> MEO2 + HO2 = HCHO # 3.34e-14^-3.53@-780;
<BR04> MEO2 + NO3 = HCHO + HO2 + NO2 # 1.30e-12;
<BR05> MEO2 + MEO2 = MEOH + HCHO # 6.39e-14^-1.80@-365;
<BR06> MEO2 + MEO2 = 2*HCHO + 2*HO2 # 7.40e-13@520;
<BR07> RO2R + NO = NO2 + HO2 # 2.60e-12@-380;
<BR08> RO2R + HO2 = XOOH # 3.80e-13@-900;
<BR09> RO2R + NO3 = NO2 + HO2 # 2.30e-12;
<BR10> RO2R + MEO2 = HO2 + 0.75*HCHO + 0.25*MEOH # 2.00e-13;
<BR11> RO2R + RO2R = HO2 # 3.50e-14;
<BR12> RO2N + NO = RNO3 # 1.0*K<BR07>;
<BR13> RO2N + HO2 = XOOH + PRD2 # 1.0*K<BR08>;
<BR14> RO2N + NO3 = NO2 + HO2 + PRD2 # 1.0*K<BR09>;
<BR15> RO2N + MEO2 = HO2 + 0.25*MEOH + PRD2 + 0.75*HCHO # 1.0*K<BR10>;
<BR16> RO2N + RO2R = HO2 + PRD2 # 1.0*K<BR11>;
<BR17> RO2N + RO2N = HO2 + 2*PRD2 # 1.0*K<BR11>;
<BR18> MECO3 + NO2 = PAN # 2.70e-28^-7.10&1.21e-11^-0.90&0.30&1.41;
<BR19> PAN = MECO3 + NO2 # 4.90e-03@12100&4.00e+16@13600&0.30&1.41;
<BR20> PAN = 0.6*MECO3 + 0.6*NO2 + 0.4*MEO2 + 0.4*CO2 + 0.4*NO3 # 1.0/<PAN>;
<BR21> MECO3 + NO = MEO2 + CO2 + NO2 # 7.50e-12@-290;
<BR22> MECO3 + HO2 = AACD + 0.3*O3 # 5.20e-13@-980;
<BR23> MECO3 + NO3 = MEO2 + CO2 + NO2 # 1.0*K<BR09>;
<BR24> MECO3 + MEO2 = 0.1*AACD + 0.1*HCHO + 0.9*HCHO + 0.9*HO2 + 0.9*MEO2 +
         0.9*CO2 # 2.00e-12@-500;
<BR25> MECO3 + RO2R = MEO2 + CO2 # 4.40e-13@-1070;
<BR26> MECO3 + RO2N = MEO2 + CO2 + HO2 + PRD2 # 1.0*K<BR25>;
<BR27> MECO3 + MECO3 = 2*MEO2 + 2*CO2 # 2.90e-12@-500;
<BR28> RCO3 + NO2 = PAN2 # 1.21e-11^-1.07@0;
<BR29> PAN2 = RCO3 + NO2 # 8.30e+16@13940;
<BR30> PAN2 = 0.6*RCO3 + 0.6*NO2 + 0.4*CCHO + 0.4*RO2R + 0.4*CO2 + 0.4*NO3
        # 1.0/<PAN>;
<BR31> RCO3 + NO = NO2 + CCHO + RO2R + CO2 # 6.70e-12@-340;
<BR32> RCO3 + HO2 = PACD + 0.25*O3 # 5.20e-13@-980;
<BR33> RCO3 + NO3 = NO2 + CCHO + RO2R + CO2 # 1.0*K<BR09>;
<BR34> RCO3 + MEO2 = CO2 + RO2R + CCHO + HCHO + HO2 # 2.00e-12@-500;
<BR35> RCO3 + RO2R = CO2 + RO2R + CCHO # 4.40e-13@-1070;
<BR36> RCO3 + RO2N = RO2R + CCHO + CO2 + HO2 + PRD2 # 1.0*K<BR35>;
<BR37> RCO3 + MECO3 = 2*CO2 + MEO2 + CCHO + RO2R # 2.90e-12@-500;
<BR38> RCO3 + RCO3 = 2*CCHO + 2*RO2R + 2*CO2 # 1.0*K<BR37>;
<BR39> BZCO3 + NO2 = PBZN # 1.37e-11;
<BR40> PBZN = BZCO3 + NO2 # 7.90e+16@14000;
<BR41> PBZN = 0.6*BZCO3 + 0.6*NO2 + 0.4*CO2 + 0.4*BZO + 0.4*R2O2 + 0.4*NO3
        # 1.0/<PAN>;
<BR42> BZCO3 + NO = NO2 + CO2 + BZO + R2O2 # 1.0*K<BR31>;
<BR43> BZCO3 + HO2 = PACD + 0.25*O3 + 4*XC # 1.0*K<BR32>;
<BR44> BZCO3 + NO3 = NO2 + CO2 + BZO + R2O2 # 1.0*K<BR09>;
<BR45> BZCO3 + MEO2 = CO2 + BZO + R2O2 + HCHO + HO2 # 1.0*K<BR34>;
<BR46> BZCO3 + RO2R = CO2 + BZO + R2O2 # 1.0*K<BR35>;
<BR47> BZCO3 + RO2N = CO2 + BZO + R2O2 + HO2 + PRD2 # 1.0*K<BR35>;
<BR48> BZCO3 + MECO3 = 2*CO2 + MEO2 + BZO + R2O2 # 1.0*K<BR37>;
<BR49> BZCO3 + RCO3 = 2*CO2 + CCHO + RO2R + BZO + R2O2 # 1.0*K<BR37>;
<BR50> BZCO3 + BZCO3 = 2*BZO + 2*R2O2 + 2*CO2 # 1.0*K<BR37>;
<BR51> MACO3 + NO2 = MAPAN # 1.0*K<BR28>;
<BR52> MAPAN = MACO3 + NO2 # 1.60e+16@13486;
<BR53> MAPAN = 0.6*MACO3 + 0.6*NO2 + 0.4*CO2 + 0.4*HCHO + 0.4*MECO3 + 0.4*NO3
        # 1.0/<PAN>;
<BR54> MACO3 + NO = NO2 + CO2 + HCHO + MECO3 # 1.0*K<BR31>;
<BR55> MACO3 + HO2 = PACD + 0.25*O3 + XC # 1.0*K<BR32>;
<BR56> MACO3 + NO3 = NO2 + CO2 + HCHO + MECO3 # 1.0*K<BR09>;
<BR57> MACO3 + MEO2 = 2*HCHO + HO2 + CO2 + MECO3 # 1.0*K<BR34>;
<BR58> MACO3 + RO2R = CO2 + HCHO + MECO3 # 1.0*K<BR35>;
<BR59> MACO3 + RO2N = CO2 + HCHO + MECO3 + HO2 + PRD2 # 1.0*K<BR35>;
<BR60> MACO3 + MECO3 = 2*CO2 + MEO2 + HCHO + MECO3 # 1.0*K<BR37>;
<BR61> MACO3 + RCO3 = HCHO + MECO3 + CCHO + RO2R + 2*CO2 # 1.0*K<BR37>;
<BR62> MACO3 + BZCO3 = HCHO + MECO3 + BZO + R2O2 + 2*CO2 # 1.0*K<BR37>;
<BR63> MACO3 + MACO3 = 2*HCHO + 2*MECO3 + 2*CO2 # 1.0*K<BR37>;
<BR64> TBUO + NO2 = RNO3 + -2*XC # 2.40e-11;
<BR65> TBUO = ACET + MEO2 # 7.50e+14@8152;
<BR66> BZO + NO2 = NPHE # 2.30e-11@-150;
<BR67> BZO + HO2 = CRES + -1*XC # 1.0*K<BR08>;
<BR68> BZO = CRES + RO2R + -1*XC # 1.00e-03;
<BR69> R2O2 + NO = NO2 # 1.0*K<BR07>;
<BR70> R2O2 + HO2 = HO2 # 1.0*K<BR08>;
<BR71> R2O2 + NO3 = NO2 # 1.0*K<BR09>;
<BR72> R2O2 + MEO2 = MEO2 # 1.0*K<BR10>;
<BR73> R2O2 + RO2R = RO2R # 1.0*K<BR11>;
<BR74> R2O2 + RO2N = RO2N # 1.0*K<BR11>;
<BR75> R2O2 + R2O2 =  # 1.0*K<BR11>;
<BR76> R2O2 + MECO3 = MECO3 # 1.0*K<BR25>;
<BR77> R2O2 + RCO3 = RCO3 # 1.0*K<BR35>;
<BR78> R2O2 + BZCO3 = BZCO3 # 1.0*K<BR35>;
<BR79> R2O2 + MACO3 = MACO3 # 1.0*K<BR35>;
<BP01> HCHO = 2*HO2 + CO # 1.0/<HCHOR-06>;
<BP02> HCHO = CO # 1.0/<HCHOM-06>;
<BP03> HCHO + OH = HO2 + CO # 5.40e-12@-135;
<BP07> HCHO + NO3 = HNO3 + HO2 + CO # 2.00e-12@2431;
<BP08> CCHO + OH = MECO3 # 4.40e-12@-365;
<BP09> CCHO = HO2 + MEO2 + CO # 1.0/<CCHO_R>;
<BP10> CCHO + NO3 = MECO3 + HNO3 # 1.40e-12@1860;
<BP11> RCHO + OH = 0.035*RO2R + 0.965*RCO3 + 0.035*CO + 0.035*CCHO
        # 5.10e-12@-405;
<BP12> RCHO = HO2 + RO2R + CO + CCHO # 1.0/<C2CHO>;
<BP13> RCHO + NO3 = RCO3 + HNO3 # 1.40e-12@1601;
<BP14> ACET + OH = MECO3 + R2O2 + HCHO # 4.56e-14^3.65@-429;
<BP15> ACET = 1.38*MEO2 + 0.62*MECO3 + 0.38*CO # 5.00e-1/<ACET-06>;
<BP16> MEK + OH = 0.376*RO2R + 0.51*MECO3 + 0.074*RCO3 + 0.039*RO2N +
         0.591*R2O2 + 0.088*HCHO + 0.504*CCHO + 0.376*RCHO + 0.3*XC
        # 1.30e-12^2.00@25;
<BP17> MEK = RO2R + MECO3 + CCHO # 1.75e-1/<MEK-06>;
<BP18> MEOH + OH = HO2 + HCHO # 2.85e-12@345;
<BP19> FACD + OH = HO2 + CO2 # 4.50e-13;
<BP20> AACD + OH = 0.491*RO2R + 0.509*MEO2 + 0.509*CO2 + 0.491*MGLY + -0.491*XC
        # 4.20e-14@-855;
<BP21> PACD + OH = RO2R + 0.143*CO2 + 0.142*CCHO + 0.4*RCHO + 0.457*BACL +
         -0.455*XC # 1.20e-12;
<BP22> COOH + OH = 0.3*OH + 0.7*MEO2 + 0.3*HCHO # 3.80e-12@-200;
<BP23> COOH = HO2 + OH + HCHO # 1.0/<COOH>;
<BP24> XOOH + OH = OH # 2.50e-11;
<BP25> XOOH = HO2 + OH # 1.0/<COOH>;
<BP30> GLY = 2*HO2 + 2*CO # 1.0/<GLY-07R>;
<BP31> GLY = HCHO + CO # 1.0/<GLY-07M>;
<BP32> GLY + OH = 0.63*HO2 + 0.37*RCO3 + 1.26*CO + -0.37*XC # 1.10e-11;
<BP33> GLY + NO3 = 0.63*HO2 + 0.37*RCO3 + HNO3 + 1.26*CO + -0.37*XC
        # 2.80e-12@2376;
<BP34> MGLY = HO2 + MECO3 + CO # 1.0/<MGLY-06>;
<BP35> MGLY + OH = MECO3 + CO # 1.50e-11;
<BP36> MGLY + NO3 = MECO3 + HNO3 + CO # 1.40e-12@1895;
<BP37> BACL = 2*MECO3 # 1.0/<BACL-07>;
<BP38> CRES + OH = 0.8*RO2R + 0.2*BZO + 0.25*MGLY + 5.05*XC # 1.70e-12@-950;
<BP39> CRES + NO3 = BZO + HNO3 + XC # 1.40e-11;
<BP40> NPHE + OH = BZO + XN # 3.50e-12;
<BP41> NPHE = HONO + 6*XC # 1.50e-3/<NO2-06>;
<BP42> NPHE = XN + 6*XC # 1.50e-2/<NO2-06>;
<BP43> BALD + OH = BZCO3 # 1.20e-11;
<BP44> BALD = 7*XC # 6.00e-2/<BALD-06>;
<BP45> BALD + NO3 = BZCO3 + HNO3 # 1.34e-12@1860;
<BP46> AFG1 + OH = 0.521*RO2R + 0.201*MECO3 + 0.217*MACO3 + 0.06*RO2N +
         0.202*R2O2 + 0.334*CO + 0.407*RCHO + 0.129*MEK + 0.107*GLY +
         0.267*MGLY + 0.284*XC # 7.40e-11;
<BP47> AFG1 + O3 = 0.522*HO2 + 0.826*OH + 0.652*RCO3 + 0.652*R2O2 + 0.522*CO +
         0.174*CO2 + 0.652*HCHO + 0.432*GLY + 0.568*MGLY + -0.872*XC
        # 9.66e-18;
<BP48> AFG1 = 1.023*HO2 + 0.173*MEO2 + 0.305*MECO3 + 0.5*MACO3 + 0.695*CO +
         0.195*GLY + 0.305*MGLY + 0.217*XC # 1.0/<AFG1>;
<BP49> AFG2 + OH = 0.521*RO2R + 0.201*MECO3 + 0.217*MACO3 + 0.06*RO2N +
         0.202*R2O2 + 0.334*CO + 0.407*RCHO + 0.129*MEK + 0.107*GLY +
         0.267*MGLY + 0.284*XC # 7.40e-11;
<BP50> AFG2 + O3 = 0.522*HO2 + 0.826*OH + 0.652*RCO3 + 0.652*R2O2 + 0.522*CO +
         0.174*CO2 + 0.652*HCHO + 0.432*GLY + 0.568*MGLY + -0.872*XC
        # 9.66e-18;
<BP51> AFG2 = PRD2 + -1*XC # 1.0/<AFG1>;
<BP52> AFG3 + OH = 0.561*RO2R + 0.117*MECO3 + 0.206*MACO3 + 0.117*RO2N +
         0.172*R2O2 + 0.114*CO + 0.274*GLY + 0.153*MGLY + 0.019*BACL +
         0.231*IPRD + 0.195*AFG1 + 0.195*AFG2 + 0.938*XC # 9.35e-11;
<BP53> AFG3 + O3 = 0.554*HO2 + 0.095*RO2R + 0.471*OH + 0.013*MECO3 +
         0.163*RCO3 + 0.007*RO2N + 0.163*R2O2 + 0.58*CO + 0.19*CO2 +
         0.163*HCHO + 0.366*GLY + 0.279*MGLY + 0.003*MACR + 0.004*MVK +
         0.003*IPRD + 0.35*AFG1 + 0.35*AFG2 + 0.139*AFG3 + -0.575*XC
        # 1.43e-17;
<BP54> MACR + OH = 0.5*RO2R + 0.5*MACO3 + 0.416*CO + 0.084*HCHO + 0.416*MEK +
         0.084*MGLY + -0.416*XC # 8.00e-12@-380;
<BP55> MACR + O3 = 0.108*HO2 + 0.208*OH + 0.1*RCO3 + 0.1*R2O2 + 0.45*CO +
         0.117*CO2 + 0.2*HCHO + 0.333*FACD + 0.9*MGLY + -0.1*XC
        # 1.40e-15@2100;
<BP56> MACR + NO3 = 0.5*RO2R + 0.5*MACO3 + 0.5*HNO3 + 0.5*CO + 0.5*XN + 1.5*XC
        # 1.50e-12@1815;
<BP57> MACR + O3P = RCHO + XC # 6.34e-12;
<BP58> MACR = 0.67*HO2 + 0.33*OH + 0.67*MECO3 + 0.33*MACO3 + 0.33*R2O2 +
         0.67*CO + 0.67*HCHO # 1.0/<MACR-06>;
<BP59> MVK + OH = 0.3*RO2R + 0.675*MECO3 + 0.025*RO2N + 0.675*R2O2 + 0.3*HCHO +
         0.675*RCHO + 0.3*MGLY + -0.725*XC # 2.60e-12@-610;
<BP60> MVK + O3 = 0.064*HO2 + 0.05*RO2R + 0.164*OH + 0.05*RCO3 + 0.475*CO +
         0.124*CO2 + 0.1*HCHO + 0.351*FACD + 0.95*MGLY + -0.05*XC
        # 8.50e-16@1520;
<BP62> MVK + O3P = 0.45*RCHO + 0.55*MEK + 0.45*XC # 4.32e-12;
<BP63> MVK = 0.4*MEO2 + 0.4*MACO3 + 0.6*CO + 0.6*PRD2 + -2.2*XC # 1.0/<MVK-06>;
<BP64> IPRD + OH = 0.67*RO2R + 0.289*MACO3 + 0.041*RO2N + 0.336*CO +
         0.055*HCHO + 0.129*CCHO + 0.013*RCHO + 0.15*MEK + 0.332*PRD2 +
         0.15*GLY + 0.174*MGLY + -0.504*XC # 6.19e-11;
<BP65> IPRD + O3 = 0.4*HO2 + 0.285*OH + 0.048*RCO3 + 0.048*R2O2 + 0.498*CO +
         0.14*CO2 + 0.125*HCHO + 0.047*CCHO + 0.21*MEK + 0.1*FACD + 0.372*PACD +
         0.023*GLY + 0.742*MGLY + -0.329*XC # 4.18e-18;
<BP66> IPRD + NO3 = 0.799*RO2R + 0.15*MACO3 + 0.051*RO2N + 0.15*HNO3 +
         0.572*CO + 0.227*HCHO + 0.218*RCHO + 0.008*MGLY + 0.572*RNO3 +
         0.278*XN + -0.815*XC # 1.00e-13;
<BP67> IPRD = 1.233*HO2 + 0.467*MECO3 + 0.3*RCO3 + 1.233*CO + 0.3*HCHO +
         0.467*CCHO + 0.233*MEK + -0.233*XC # 1.0/<MACR-06>;
<BP68> PRD2 + OH = 0.472*HO2 + 0.379*RO2R + 0.029*MECO3 + 0.049*RCO3 +
         0.071*RO2N + 0.094*R2O2 + 0.213*HCHO + 0.084*CCHO + 0.545*RCHO +
         0.115*MEK + 0.336*PRD2 + 0.877*XC # 1.55e-11;
<BP69> PRD2 = 0.913*RO2R + 0.4*MECO3 + 0.6*RCO3 + 0.087*RO2N + 0.677*R2O2 +
         0.303*HCHO + 0.163*CCHO + 0.78*RCHO + -0.091*XC # 4.86e-3/<MEK-06>;
<BP70> RNO3 + OH = 0.189*HO2 + 0.305*RO2R + 0.332*NO2 + 0.175*RO2N +
         0.671*R2O2 + 0.011*HCHO + 0.429*CCHO + 0.037*RCHO + 0.004*ACET +
         0.18*MEK + 0.039*PRD2 + 0.494*RNO3 + 0.174*XN + 0.04*XC # 7.20e-12;
<BP71> RNO3 = 0.344*HO2 + 0.554*RO2R + NO2 + 0.102*RO2N + 0.167*R2O2 +
         0.135*HCHO + 0.444*CCHO + 0.137*RCHO + 0.008*ACET + 0.207*MEK +
         0.451*PRD2 + 0.396*XC # 1.0/<IC3ONO2>;
<BE01> CH4 + OH = MEO2 # 1.85e-12@1690;
<BE02> ETHE + OH = RO2R + 1.61*HCHO + 0.195*CCHO
        # 1.00e-28^-4.50&8.80e-12^-0.85&0.60&1.00;
<BE03> ETHE + O3 = 0.16*HO2 + 0.16*OH + 0.51*CO + 0.12*CO2 + HCHO + 0.37*FACD
        # 9.14e-15@2580;
<BE04> ETHE + NO3 = RO2R + RCHO + XN + -1*XC # 3.30e-12^2.00@2880;
<BE05> ETHE + O3P = 0.8*HO2 + 0.29*RO2R + 0.51*MEO2 + 0.788*CO + 0.278*HCHO +
         0.1*CCHO + 0.012*GLY + 0.2*XC # 1.07e-11@800;
<BE06> ISOP + OH = 0.907*RO2R + 0.093*RO2N + 0.079*R2O2 + 0.624*HCHO +
         0.23*MACR + 0.32*MVK + 0.357*IPRD + -0.167*XC # 2.54e-11@-410;
<BE07> ISOP + O3 = 0.066*HO2 + 0.266*OH + 0.192*MACO3 + 0.008*RO2N +
         0.192*R2O2 + 0.275*CO + 0.122*CO2 + 0.592*HCHO + 0.1*PRD2 +
         0.204*FACD + 0.39*MACR + 0.16*MVK + 0.15*IPRD + -0.559*XC
        # 7.86e-15@1912;
<BE08> ISOP + NO3 = 0.749*RO2R + 0.187*NO2 + 0.064*RO2N + 0.187*R2O2 +
         0.936*IPRD + 0.813*XN + -0.064*XC # 3.03e-12@448;
<BE09> ISOP + O3P = 0.25*MEO2 + 0.24*MACO3 + 0.01*RO2N + 0.24*R2O2 + 0.24*HCHO +
         0.75*PRD2 + -1.01*XC # 3.50e-11;
<BE10> ACYE + OH = 0.3*HO2 + 0.7*OH + 0.3*CO + 0.3*FACD + 0.7*GLY
        # 5.50e-30^-2.00&8.30e-13&0.60&1.00;
<BE11> ACYE + O3 = 1.5*HO2 + 0.5*OH + 1.5*CO + 0.5*CO2 # 1.00e-14@4100;
<BE12> BENZ + OH = 0.57*HO2 + 0.29*RO2R + 0.116*OH + 0.024*RO2N + 0.29*GLY +
         0.57*CRES + 0.029*AFG1 + 0.261*AFG2 + 0.116*AFG3 + -0.976*XC
        # 2.33e-12@193;
!
! Atmospheric Lumped VOC Mechanism
! Created from MECH09A.XLS 25-Jan-2010 14:17
!
<BL01> ALK1 + OH = RO2R + CCHO # 1.34e-12^2.00@499;
<BL02> ALK2 + OH = 0.965*RO2R + 0.035*RO2N + 0.261*RCHO + 0.704*ACET +
         -0.105*XC # 1.49e-12^2.00@87;
<BL03> ALK3 + OH = 0.695*RO2R + 0.236*TBUO + 0.07*RO2N + 0.558*R2O2 +
         0.026*HCHO + 0.445*CCHO + 0.122*RCHO + 0.024*ACET + 0.332*MEK +
         -0.046*XC # 1.51e-12@-126;
<BL04> ALK4 + OH = 0.83*RO2R + 0.01*MEO2 + 0.011*MECO3 + 0.149*RO2N +
         0.933*R2O2 + 0.002*CO + 0.029*HCHO + 0.438*CCHO + 0.236*RCHO +
         0.426*ACET + 0.106*MEK + 0.146*PRD2 + -0.119*XC # 3.75e-12@-44;
<BL05> ALK5 + OH = 0.647*RO2R + 0.353*RO2N + 0.958*R2O2 + 0.04*HCHO +
         0.106*CCHO + 0.209*RCHO + 0.071*ACET + 0.086*MEK + 0.407*PRD2 +
         2.004*XC # 2.70e-12@-374;
<BL06> OLE1 + OH = 0.904*RO2R + 0.001*MEO2 + 0.095*RO2N + 0.234*R2O2 +
         0.7*HCHO + 0.301*CCHO + 0.47*RCHO + 0.005*ACET + 0.119*PRD2 +
         0.026*MACR + 0.008*MVK + 0.006*IPRD + 0.822*XC # 6.18e-12@-501;
<BL07> OLE1 + O3 = 0.116*HO2 + 0.04*RO2R + 0.193*OH + 0.104*MEO2 + 0.004*RO2N +
         0.023*R2O2 + 0.368*CO + 0.125*CO2 + 0.5*HCHO + 0.154*CCHO +
         0.384*RCHO + 0.002*ACET + 0.006*MEK + 0.189*PRD2 + 0.185*FACD +
         0.022*AACD + 0.112*PACD + 0.69*XC # 3.15e-15@1701;
<BL08> OLE1 + NO3 = 0.824*RO2R + 0.176*RO2N + 0.488*R2O2 + 0.009*CCHO +
         0.002*RCHO + 0.024*ACET + 0.546*RNO3 + 0.454*XN + 0.572*XC
        # 4.73e-13@1047;
<BL09> OLE1 + O3P = 0.45*RCHO + 0.437*MEK + 0.113*PRD2 + 1.224*XC
        # 1.49e-11@326;
<BL10> OLE2 + OH = 0.914*RO2R + 0.086*RO2N + 0.052*R2O2 + 0.209*HCHO +
         0.788*CCHO + 0.481*RCHO + 0.136*ACET + 0.076*MEK + 0.022*PRD2 +
         0.027*MACR + 0.002*MVK + 0.037*IPRD + 0.111*XC # 1.26e-11@-488;
<BL11> OLE2 + O3 = 0.093*HO2 + 0.039*RO2R + 0.423*OH + 0.29*MEO2 + 0.147*MECO3 +
         0.008*RCO3 + 0.003*RO2N + 0.161*R2O2 + 0.297*CO + 0.162*CO2 +
         0.26*HCHO + 0.495*CCHO + 0.333*RCHO + 0.048*ACET + 0.032*MEK +
         0.042*PRD2 + 0.033*FACD + 0.061*AACD + 0.222*PACD + 0.028*MACR +
         0.021*MVK + 0.125*XC # 8.14e-15@1255;
<BL12> OLE2 + NO3 = 0.423*RO2R + 0.409*NO2 + 0.033*MEO2 + 0.136*RO2N +
         0.762*R2O2 + 0.074*HCHO + 0.546*CCHO + 0.154*RCHO + 0.11*ACET +
         0.002*MEK + 0.026*MVK + 0.007*IPRD + 0.322*RNO3 + 0.269*XN + 0.114*XC
        # 2.20e-13@-382;
<BL13> OLE2 + O3P = 0.014*HO2 + 0.007*RO2R + 0.007*MACO3 + 0.001*RO2N +
         0.006*R2O2 + 0.006*CO + 0.074*RCHO + 0.709*MEK + 0.202*PRD2 +
         0.006*MACR + 0.666*XC # 1.43e-11@-111;
<BL14> ARO1 + OH = 0.166*HO2 + 0.482*RO2R + 0.284*OH + 0.068*RO2N + 0.077*PRD2 +
         0.218*GLY + 0.138*MGLY + 0.166*CRES + 0.049*BALD + 0.164*AFG1 +
         0.193*AFG2 + 0.284*AFG3 + 0.002*XC # 6.15e-12;
<BL15> ARO2 + OH = 0.108*HO2 + 0.58*RO2R + 0.202*OH + 0.11*RO2N + 0.035*PRD2 +
         0.116*GLY + 0.286*MGLY + 0.104*BACL + 0.108*CRES + 0.039*BALD +
         0.217*AFG1 + 0.21*AFG2 + 0.282*AFG3 + 1.486*XC # 2.57e-11;
<BL16> TERP + OH = 0.759*RO2R + 0.042*RCO3 + 0.2*RO2N + 0.388*R2O2 + 0.001*CO +
         0.264*HCHO + 0.533*RCHO + 0.036*ACET + 0.005*MEK + 0.255*PRD2 +
         0.009*MGLY + 0.014*BACL + 0.002*MVK + 0.001*IPRD + 5.056*XC
        # 1.87e-11@-435;
<BL17> TERP + O3 = 0.052*HO2 + 0.067*RO2R + 0.585*OH + 0.126*MECO3 +
         0.149*RCO3 + 0.203*RO2N + 0.808*R2O2 + 0.185*CO + 0.045*CO2 +
         0.229*HCHO + 0.22*RCHO + 0.165*ACET + 0.004*MEK + 0.409*PRD2 +
         0.107*FACD + 0.043*PACD + 0.001*GLY + 0.002*MGLY + 0.055*BACL +
         0.001*MACR + 0.001*IPRD + 3.526*XC # 9.57e-16@785;
<BL18> TERP + NO3 = 0.162*RO2R + 0.421*NO2 + 0.019*RCO3 + 0.397*RO2N +
         1.347*R2O2 + 0.01*CO + 0.017*HCHO + 0.001*CCHO + 0.509*RCHO +
         0.175*ACET + 0.001*MGLY + 0.003*MACR + 0.001*MVK + 0.002*IPRD +
         0.163*RNO3 + 0.416*XN + 4.473*XC # 1.28e-12@-490;
<BL19> TERP + O3P = 0.147*RCHO + 0.853*PRD2 + 4.441*XC # 3.71e-11;
!
! Base Chlorine Mechanism
! Created from MECH09A.XLS 25-Jan-2010 14:17
!
<CI01> CL2 = 2*CL # 1.0/<CL2>;
<CI02> CL + NO + M = CLNO # 7.60e-32^-1.80;
<CI03> CLNO = CL + NO # 1.0/<CLNO-06>;
<CI04> CL + NO2 = CLONO # 1.30e-30^-2.00&1.00e-10^-1.00&0.60&1.00;
<CI05> CL + NO2 = CLNO2 # 1.80e-31^-2.00&1.00e-10^-1.00&0.60&1.00;
<CI06> CLONO = CL + NO2 # 1.0/<CLONO>;
<CI07> CLNO2 = CL + NO2 # 1.0/<CLNO2>;
<CI08> CL + HO2 = HCL # 3.44e-11^-0.56;
<CI09> CL + HO2 = CLO + OH # 9.41e-12^2.10;
<CI10> CL + O3 = CLO # 2.80e-11@250;
<CI11> CL + NO3 = CLO + NO2 # 2.40e-11;
<CI12> CLO + NO = CL + NO2 # 6.20e-12@-295;
<CI13> CLO + NO2 = CLONO2 # 1.80e-31^-3.40&1.50e-11^-1.90&0.60&1.00;
<CI14> CLONO2 = CLO + NO2 # 1.0/<CLONO2-1>;
<CI15> CLONO2 = CL + NO3 # 1.0/<CLONO2-2>;
<CI16> CLONO2 = CLO + NO2 # 4.48e-05^-1.00@12530&3.71e+15^3.50@12530&0.60&1.00;
<CI17> CL + CLONO2 = CL2 + NO3 # 6.20e-12@-145;
<CI18> CLO + HO2 = HOCL # 2.20e-12@-340;
<CI19> HOCL = OH + CL # 1.0/<HOCL-06>;
<CI20> CLO + CLO = 0.29*CL2 + 1.42*CL # 1.25e-11@1960;
<CI21> OH + HCL = CL # 1.70e-12@230;
<CI22> CL + H2 = HCL + HO2 # 3.90e-11@2310;
<CP01> HCHO + CL = HCL + HO2 + CO # 8.10e-11@30;
<CP02> CCHO + CL = HCL + MECO3 # 8.00e-11;
<CP03> MEOH + CL = HCL + HO2 + HCHO # 5.50e-11;
<CP04> RCHO + CL = HCL + 0.1*RO2R + 0.9*RCO3 + 0.1*CO + 0.1*CCHO # 1.23e-10;
<CP05> ACET + CL = HCL + MECO3 + R2O2 + HCHO # 7.70e-11@1000;
<CP06> MEK + CL = HCL + 0.84*RO2R + 0.085*MECO3 + 0.036*RCO3 + 0.039*RO2N +
         0.135*R2O2 + 0.065*HCHO + 0.07*CCHO + 0.84*RCHO + 0.763*XC # 3.60e-11;
<CP07> RNO3 + CL = HCL + 0.055*HO2 + 0.547*RO2R + 0.197*NO2 + 0.202*RO2N +
         0.735*R2O2 + 0.045*HCHO + 0.3*CCHO + 0.029*RCHO + 0.003*ACET +
         0.059*MEK + 0.058*PRD2 + 0.602*RNO3 + 0.201*XN + -0.149*XC # 1.92e-10;
<CP08> PRD2 + CL = HCL + 0.314*HO2 + 0.541*RO2R + 0.007*MECO3 + 0.022*RCO3 +
         0.116*RO2N + 0.138*R2O2 + 0.237*HCHO + 0.109*CCHO + 0.789*RCHO +
         0.051*MEK + 0.156*PRD2 + 1.262*XC # 2.00e-10;
<CP09> GLY + CL = HCL + 0.63*HO2 + 0.37*RCO3 + 1.26*CO + -0.37*XC
        # 8.10e-11@30;
<CP10> MGLY + CL = HCL + MECO3 + CO # 8.00e-11;
<CP11> CRES + CL = HCL + RO2R + -1*R2O2 + BALD # 6.20e-11;
<CP12> BALD + CL = HCL + BZCO3 # 8.00e-11;
<CP13> XOOH + CL = CL # 1.66e-10;
<CP16> MACR + CL = 0.25*HCL + 0.802*RO2R + 0.165*MACO3 + 0.033*RO2N + 0.541*CO +
         0.082*IPRD + 0.18*CLCCHO + 0.541*CLACET + 0.208*XC # 3.85e-10;
<CP17> MVK + CL = 0.322*RO2R + 0.625*MECO3 + 0.053*RO2N + 0.961*R2O2 +
         0.947*CLCCHO + 0.538*XC # 2.32e-10;
<CP18> IPRD + CL = 0.401*HCL + 0.084*HO2 + 0.712*RO2R + 0.154*MACO3 +
         0.051*RO2N + 0.018*R2O2 + 0.498*CO + 0.195*HCHO + 0.017*MGLY +
         0.115*IPRD + 0.051*AFG1 + 0.051*AFG2 + 0.14*CLCCHO + 0.42*CLACET +
         0.709*XC # 4.12e-10;
<CP19> CLCCHO = HO2 + RO2CL + CO + HCHO # 1.0/<CLCCHO>;
<CP20> CLCCHO + OH = RCO3 + -1*XC # 3.10e-12;
<CP21> CLCCHO + CL = HCL + RCO3 + -1*XC # 1.29e-11;
<CP22> CLACET = RO2CL + MECO3 + HCHO # 5.00e-1/<CLACET>;
<CR01> RO2CL + NO = NO2 + CL # 1.0*K<BR07>;
<CR02> RO2CL + HO2 = XOOH # 1.0*K<BR08>;
<CR03> RO2CL + NO3 = NO2 + CL # 1.0*K<BR09>;
<CR04> RO2CL + MEO2 = 0.5*CL + 0.5*HO2 + 0.75*HCHO + 0.25*MEOH # 1.0*K<BR10>;
<CR05> RO2CL + RO2R = 0.5*CL + 0.5*HO2 # 1.0*K<BR11>;
<CR06> RO2CL + R2O2 = RO2CL # 1.0*K<BR11>;
<CR07> RO2CL + RO2N = 0.5*CL + 0.5*HO2 + 0.5*MEK + 0.5*PRD2 + XC # 1.0*K<BR11>;
<CR08> RO2CL + RO2CL = CL # 1.0*K<BR11>;
<CR09> RO2CL + MECO3 = MEO2 + CO2 # 1.0*K<BR35>;
<CR10> RO2CL + RCO3 = CO2 + RO2R + CCHO # 1.0*K<BR35>;
<CR11> RO2CL + BZCO3 = CO2 + BZO + R2O2 # 1.0*K<BR35>;
<CR12> RO2CL + MACO3 = CO2 + HCHO + MECO3 # 1.0*K<BR35>;
<CE01> CH4 + CL = HCL + MEO2 # 7.30e-12@1280;
<CE02> ETHE + CL = RO2R + R2O2 + HCHO + CLCHO
        # 1.60e-29^-3.30&3.10e-10^-1.00&0.60&1.00;
<CE03> ISOP + CL = 0.15*HCL + 0.738*RO2R + 0.177*RO2CL + 0.085*RO2N +
         0.253*R2O2 + 0.275*HCHO + 0.177*MVK + 0.671*IPRD + 0.067*CLCCHO +
         0.018*XC # 4.80e-10;
<CE04> ACYE + CL = HO2 + CO + XC # 5.20e-30^-2.40&2.20e-10&0.60&1.00;
!
! Chlorine + Atmospheric Lumped VOC Mechanism
! Created from MECH09A.XLS 25-Jan-2010 14:17
!
<BC01> ALK1 + CL = HCL + RO2R + CCHO # 5.95e-11;
<BC02> ALK2 + CL = HCL + 0.97*RO2R + 0.03*RO2N + 0.482*RCHO + 0.488*ACET +
         -0.09*XC # 1.37e-10;
<BC03> ALK3 + CL = HCL + 0.835*RO2R + 0.094*TBUO + 0.07*RO2N + 0.526*R2O2 +
         0.078*HCHO + 0.34*CCHO + 0.343*RCHO + 0.075*ACET + 0.253*MEK + 0.18*XC
        # 1.86e-10;
<BC04> ALK4 + CL = HCL + 0.827*RO2R + 0.003*MEO2 + 0.004*MECO3 + 0.165*RO2N +
         0.91*R2O2 + 0.003*CO + 0.034*HCHO + 0.287*CCHO + 0.412*RCHO +
         0.247*ACET + 0.076*MEK + 0.13*PRD2 + 0.327*XC # 2.63e-10;
<BC05> ALK5 + CL = HCL + 0.647*RO2R + 0.352*RO2N + 0.894*R2O2 + 0.022*HCHO +
         0.08*CCHO + 0.258*RCHO + 0.044*ACET + 0.041*MEK + 0.378*PRD2 +
         2.368*XC # 4.21e-10;
<BC06> OLE1 + CL = 0.308*HCL + 0.902*RO2R + 0.098*RO2N + 0.518*R2O2 +
         0.025*HCHO + 0.146*CCHO + 0.051*RCHO + 0.188*MACR + 0.014*MVK +
         0.027*IPRD + 0.225*CLCCHO + 0.396*CLACET + 1.361*XC # 3.55e-10;
<BC07> OLE2 + CL = 0.263*HCL + 0.447*RO2R + 0.448*RO2CL + 0.001*MEO2 +
         0.104*RO2N + 0.619*R2O2 + 0.228*HCHO + 0.361*CCHO + 0.3*RCHO +
         0.081*ACET + 0.04*MEK + 0.049*MACR + 0.055*MVK + 0.179*IPRD +
         0.012*CLCCHO + 0.18*CLACET + 0.247*XC # 3.83e-10;
<BC08> ARO1 + CL = 0.88*RO2R + 0.12*RO2N + 0.21*PRD2 + 0.671*BALD + 0.323*XC
        # 1.00e-10;
<BC09> ARO2 + CL = 0.842*RO2R + 0.158*RO2N + 0.224*PRD2 + 0.618*BALD + 2.382*XC
        # 2.18e-10;
<BC10> TERP + CL = 0.548*HCL + 0.252*RO2R + 0.068*RO2CL + 0.034*MECO3 +
         0.05*RCO3 + 0.016*MACO3 + 0.582*RO2N + 1.938*R2O2 + 0.035*CO +
         0.158*HCHO + 0.185*RCHO + 0.274*ACET + 0.007*GLY + 0.003*BACL +
         0.003*MVK + 0.158*IPRD + 0.006*AFG1 + 0.006*AFG2 + 0.001*AFG3 +
         0.109*CLCCHO + 3.543*XC # 5.46e-10;
!
endmech